A polyvinyl alcohol-based mixed matrix membrane with uniformly distributed Schiff base network-1 for ethanol dehydration

In this study, Schiff base network (SNW)-1 nanoparticles with high hydrophilicity and large specific surface area were used to prepare polyvinyl alcohol (PVA)-based mixed matrix membranes (MMMs), which were evaluated for ethanol dehydration. Because of the low difference of density between SNW-1 and PVA, the as-prepared nanoparticles can be uniformly distributed into the PVA active layer. The effects of SNW-1 loading, feed temperature, and water concentration on pervaporation (PV) performance were further studied. The results showed the MMM with 10 wt% of SNW-1 loading exhibited a separation factor of 1,501 and a permeation flux of 187 g m⁻² h⁻¹ for feeding 95 wt% ethanol/water binary solution at 75°C. Overall, the SNW-1/PVA MMMs showed great prospect in ethanol dehydration via PV.     

Output feedback tracking control for rigid body attitude via immersion and invariance angular velocity observers

A novel immersion and invariance (I&I) angular velocity observer is presented for the attitude tracking control of a rigid body with the lack of angular rate. Global exponential convergence of angular velocity estimate errors are guaranteed by an innovative filter design for the estimates' Euclidean norm. The proposed method requires fewer filter states compared with existing I&I angular velocity observer designs, which achieves a simpler closed-loop structure (dynamic reduction). The observer synthesis and convergence are independent of the control torque, which leads to much convenience in establishing “separation property” when combining a proportional-derivative attitude tracking controller driven by angular velocity estimates. A rigorous stability analysis is provided to ensure the (almost) global asymptotic convergence of the overall closed-loop tracking errors, and several numerical simulations are carried out to demonstrate the effectiveness of the combined implementation of proposed angular velocity observer and full-state feedback attitude tracking controller.     

釉面分相对无铅CuO-MnO2系金属光泽釉的影响

以钙系生料釉为基础,引入结晶剂CuO、MnO₂制备无铅CuO-MnO₂系金属光泽釉;结合XRD、SEM-EDS进行物相组成定性分析和显微结构表征,系统探究外加TiO₂、V₂O₅以及玻璃粉对金属光泽釉釉面分相的影响。研究表明:一定量的TiO₂、V₂O₅引入能有效促进釉面的分相,将玻璃粉部分替换基础釉中的钾长石能使得釉熔体的高温粘度降低,并进一步加剧釉面分相,促进CuMn₂O₄铜锰尖晶石在釉层表面的析出和富集;当TiO₂引入量为2%,V₂O₅引入量为1%,玻璃粉引入量为25%(同为质量分数)时,金属光泽釉釉面效果最佳。     

黔西南某中高硫煤脱硫过程中微量元素的分配特性研究

为探究黔西南某中高硫煤中微量元素的富集程度,以及在脱硫降灰提质利用过程中微量元素的分配特性,通过摇床对其脱硫降灰进行了试验研究,并在合适的分选工艺条件下,考察了原煤、精煤和尾煤产品中微量元素的分配特征。通过“一粗一精一扫”重选,可获得产率32.83%、硫分0.96%、灰分11.16%的合格精煤产品。分选产品微量元素分析结果表明,该分选工艺对Cu、Sb、As、Co、Mo、TI、Ni等有害元素具有较好的脱除效果,并能一定程度富集锂和稀土等有价微量元素。通过此工艺可分别回收28.73%和47.37%的锂至精煤和中煤产品,精煤煤灰中Li₂O理论含量达5 258 μg/g,具有综合回收利用价值。研究结果可为该类中高硫煤炭资源的清洁与综合利用提供参考。     

攀西地区白马辉长岩型超低品位钒钛磁铁矿选铁试验研究

论文以攀西地区白马辉长岩型超低品位钒钛磁铁矿为研究对象,查明了该矿石中化学组分、矿物组成、铁和TiO₂的相态。在此基础上进行了多粒级多磁场梯度干式磁选抛尾试验,通过铁和TiO₂的相态分析阐述了干式磁选抛尾的合理性；进行了干式磁选精矿阶段磨矿阶段选别试验,二段磁选在-200目占80%细度下获得了TFe 57.78%、TiO₂ 7.72%、V₂O₅ 0.69%的铁精矿,铁精矿产率为12.93%、铁回收率51.56%,相对磁性铁回收率为98.70%,V₂O₅回收率78.26%。结果表明该矿石虽然铁品位低,仍具综合回收利用价值。      

High‐performance printable paper‐like composites derived from plastic flexible film wastes

Owing to lack of proper recycling methods, plastic flexible film wastes are usually directly discarded or incinerated, which brings about severe environmental pollution. Therefore, converting plastic wastes into value‐added products has received more and more attention in recent years. In this work, paper‐like composites derived from plastic flexible film wastes were prepared via the thermally induced phase separation method by adding polyethylene‐graft‐maleic anhydride (PE‐g‐MAH) as a compatibilizer and fumed silica as an additive. The resulting paper‐like composites were characterized by SEM and infrared spectroscopy. Other properties such as mechanical properties, thermal properties, whiteness, printability and adsorption performance were also tested in detail. It was found that remarkable enhancements in mechanical, thermal and printable properties of the paper‐like composites were obtained when nano‐SiO₂ loading was 2.5–3 wt%. Uniformly distributed holes that can endow good printability by providing space for ink or other functional molecules were observed by using SEM. Furthermore, the CIE whiteness value of the resulting composites can reach 91.6%–96.7% on adding nano‐SiO₂. Additionally, the paper‐like composites integrating nano‐SiO₂ and PE‐g‐MAH exhibited good solid ink affinity and high water or oil adsorption capacity. Thus, according to this research, high‐performance printable paper‐like composites used as major components of multifunctional papers can be prepared based on plastic flexible film wastes. © 2019 Society of Chemical Industry     

基于VOF模型的层叠器流动过程分析及流道结构优化

基于FLUENT软件的流体体积(VOF)模型研究了不同壁面滑移程度以及不同流道结构参数下4层等厚熔体通过层叠器倍增为8层熔体时,流道中熔体的分层情况变化。结果表明,壁面滑移程度的降低会促使熔体在上下壁面聚集,进而导致上下壁面处熔体层厚增加;汇流段与出口段间圆角半径、汇流段扩压角和平衡段长度这3个结构参数则只会影响熔体在左右壁面的聚集,进而影响各层熔体的尺寸精度,且其中扩压角的影响程度最大,平衡段长度次之,圆角半径的影响较小。     

W型铸铝水冷机座压铸新工艺

本文介绍了一种环保能源牵引电机及发电机定子机座的制造方法。通过压铸模具的设计,在内筒体上铸出W型水道和W型阴槽及焊缝保护法兰;在外筒体上铸出W型阳槽,内外筒体压力铸造;然后在压力状态下通过W型导向,对内外筒体进行预热压装;最后内外筒体进行组焊制成电机定子水冷机座。本工艺结构巧妙,工序简单,防漏水、窜水,结构可靠。